New octa-benzothiazole substituted metal free and metallophthalocyanines: Synthesis, characterization and electrochemical studies
نویسندگان
چکیده
The synthesis, spectroscopic and electrochemical properties of the following octa-benzothiazole substituted metal-free (4), cobalt(II) (5) zinc (II) (6) phthalocyanines are reported for first time. novel have been characterized by FT-IR, NMR spectroscopy, electronic spectroscopy mass spectroscopy. Voltammetric analysis benzothiazole group were determined cyclic (CV) square wave voltammetry (SWV). According to results, revealed metal ligand-based quasi-reversible reduction oxidation processes.
منابع مشابه
Synthesis and characterization of new metal-free and metallophthalocyanines containing spherical or cylindrical macrotricyclic moieties
New metal-free phthalocyanines (8–9) fused in peripheral positions with four tetraazadithiahexaoxa supercryptands were synthesized by tricyclotetramerization of isoindolinediimine derivatives of supercryptands (6–7). Metallophthalocyanines (10–11) were prepared by the reaction of the metal-free phthalocyanines with metal salts or cyclotetramerization of dicyano compounds (4–5) and anhydrous sal...
متن کاملSynthesis and Characterization of New Metal-free and Metallophthalocyanines Containing Macrobicyclic Moieties
Supramolecular Chemistry Publication details, including instructions for authors and subscription information: http://www.informaworld.com/smpp/title~content=t713649759 Synthesis and Characterization of New Metal-free and Metallophthalocyanines Containing Macrobicyclic Moieties Ahmet Bİlgİn a; Yaşar Gök b a Faculty of Education, Kocaeli University, Kocaeli, Turkey b Department of Chemistry, Pam...
متن کاملSynthesis and characterization of new metal-free and metallophthalocyanines fused a-methylferrocenylmethoxy units
Synthesis of metal-free and metallophthalocyanines bearing a-methylferrocenylmethoxy units was described. Precursor 3 required for the preparation of phthalocyanines 4–9, was synthsized by the nucleophilic aromatic substitution reaction between a-methylferrocenylmethanol and 4-nitrophthalonitrile in dry DMF. The metal-free phthalocyanine 4 was prepared from 4-(amethylferrocenylmethoxy)phthaloni...
متن کاملsynthesis and characterization of some new cyclometalated organoplatinum(ii) complexes containing phosphite ligand
در این تحقیق روشی جهت سنتز یک سری از کمپلکس های پلاتین (ii) حاوی لیگاند های دهنده ی فسفری شامل فسفیت و فسفین ارائه شده است. واکنش پیش ماده ی پلاتین (ii)،trans/cis- [ptcl2(sme2)2] ، با 2 اکی مولار از لیگاند p(oph)3در حلال بنزن کمپلکس1، cis-[ptcl2(p(oph)3)2] را تولید می نماید. جهت سنتز کمپلکس سایکلو متال فسفیتی، کمپلکس 1 با 1 اکی والان واکنشگر ptcl2 در حلال زایلن در شرایط رفلاکس زیر گاز آرگون م...
Synthesis, Characterization and Biological Activity of Various Substituted Benzothiazole Derivatives
A series of 2-(benzo[d]thiazol-2-ylthio)-N-(2-oxoindolin-3-ylidene)acetohydrazide (3a3g), 2-(benzo [d]thiazol-2-ylthio)-N-(2,4’-dioxospiro[indolin-3,2’-thiazolidin)-3’yl)acetamide (4a-4g) and 2'-((benzo[d]thiazol-2-ylthio)methyl)spiro[indoline-3,5'thiazolo[4,3-b][1,3,4]oxadiazol]-2-ones (5a-5g) have been synthesized and screened for their anti-inflammatory, analgesic and antibacterial activitie...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Turkish journal of analytical chemistry
سال: 2021
ISSN: ['2687-6698']
DOI: https://doi.org/10.51435/turkjac.935057